Matter is incredibly diverse, existing in various forms, each with distinct properties and behaviours. Matter can be categorised into two groups: pure substances and impure substances, which are also known as mixtures.
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A homogeneous mixture, also known as a solution, is a type of mixture where all the different substances or components are thoroughly mixed together on a molecular level. This results in a uniform distribution of the components throughout the mixture, creating a single and consistent phase. One remarkable characteristic of solutions is that their particles are extremely small, often less than 1 nanometer in size. In other words, you can't easily see or differentiate the individual components with the naked eye.
Key characteristics of homogeneous mixtures include:
a) Uniform Composition: In a homogeneous mixture, the composition is the same throughout the entire mixture. This means that every part of the mixture contains the same proportion of each component.
b) No Visible Boundaries: Unlike some other types of mixtures where you can see distinct boundaries between the components, homogeneous mixtures have no visible boundaries. The components are so well-mixed that they appear as a single substance.
c) Stable Structure: Homogeneous mixtures are stable and do not separate over time. The components remain evenly distributed, even when the mixture is left undisturbed.
d) Transparent Appearance: Many homogeneous mixtures are transparent or translucent because the components are evenly distributed at the molecular level, allowing light to pass through without scattering.
e) Examples: Some common examples of homogeneous mixtures include salt dissolved in water, sugar dissolved in tea or coffee, and air (which is a mixture of gases like nitrogen, oxygen, and trace amounts of other gases).
A heterogeneous mixture is a type of mixture in which the different substances or components are not uniformly mixed and can be easily distinguished from one another. Unlike homogeneous mixtures, the components in a heterogeneous mixture are not evenly distributed at the molecular level, and you can often see distinct boundaries or separations between the different components.
Key characteristics of heterogeneous mixtures include:
a) Non-Uniform Composition: In a heterogeneous mixture, the composition varies from one part of the mixture to another. This means that different regions of the mixture may have different proportions of the components.
b) Visible Boundaries: Unlike homogeneous mixtures where the components blend seamlessly, heterogeneous mixtures have visible boundaries or separations between the components. You can see and identify the different components with the naked eye.
c) Uneven Distribution: The components in a heterogeneous mixture do not mix thoroughly on a molecular level. Instead, they may be present in different sizes or concentrations, leading to variations in appearance and properties.
d) Potential Separation: Because the components are not uniformly mixed, heterogeneous mixtures can often be separated using physical methods such as filtration, decantation, or sedimentation.
e) Examples: Some common examples of heterogeneous mixtures include a salad with various vegetables, a mixture of sand and water, and a mixture of oil and water. Each of these mixtures contains distinct components that can be easily identified.
f) Tyndall Effect: Both suspensions and colloids show the Tyndall effect. Tyndall effect refers to the scattering of light by particles in a medium. When a beam of light is passed through a fine suspension or a colloid, the light gets scattered by the particles present in the mixture, making the path of the light visible. This effect is commonly observed when you see a beam of sunlight passing through a foggy room or when a flashlight is shone through a mist.
g) Classification: Heterogeneous mixtures can be further classified into two different types based on the size of the particles and the nature of the components: suspensions and colloids.
Dispersed Medium |
Dispersing Medium |
Type of Colloid |
Example |
Solid |
Gas |
Solid Aerosol |
Smoke, dust in the air |
Liquid |
Gas |
Liquid Aerosol |
Fog, mist |
Gas |
Liquid |
Foam |
Whipped cream, shaving foam |
Liquid |
Liquid |
Emulsion |
Milk, mayonnaise |
Solid |
Liquid |
Sol |
Paint, ink |
Gas |
Solid |
Foam |
Bread, sponge |
Liquid |
Solid |
Gel |
Jellies, gelatin desserts |
Solid |
Solid |
Solid Sol |
Coloured gemstones, opals |
Solubility refers to the maximum amount of a substance (solute) that can dissolve in a given amount of another substance (solvent) at a specific temperature to create a saturated solution. In other words, it's the highest concentration of solute that the solvent can hold at that temperature without any more solute being able to dissolve. Solubility is typically measured in terms of how much solute can dissolve in 100 grams of the solvent under the given conditions.
Solubility is influenced by several factors. These factors determine how much of a solute can dissolve in a given solvent under specific conditions. Some key factors affecting solubility are:
a) Temperature: In general, as temperature increases, the solubility of solid solutes in liquids also increases. This is because higher temperatures provide more energy to the particles, allowing them to break apart and mix more readily. However, for some substances, like gases in liquids, higher temperatures can actually decrease solubility. This is because gases tend to escape from liquids as the temperature rises.
b) Pressure: Pressure has a significant impact on the solubility of gases in liquids. When pressure increases, the solubility of gases in liquids generally increases as well. This is why, for example, carbon dioxide gas dissolves in soda under pressure, but bubbles out when the pressure is released after opening the bottle.
For solids and liquids, changes in pressure have minimal impact on solubility.
c) Nature of Solute and Solvent: The chemical nature of the solute and solvent greatly influences solubility. Similar substances often dissolve well in each other (like dissolving salt in water), while dissimilar substances may have lower solubility (like oil in water).
d) Particle Size: Smaller particles of a solute have a larger surface area in contact with the solvent, which can lead to faster dissolution. Finely powdered substances tend to dissolve more quickly than larger chunks.
e) Stirring: Agitating or stirring the mixture increases the contact between the solute and solvent, facilitating faster dissolution. This is especially important for solid solutes.
f) Type of Solvent: Different solvents have varying abilities to dissolve different solutes. A solvent with similar properties to the solute is more likely to dissolve it effectively.
g) Presence of Other Solutes: The presence of other solutes in the solution can impact the solubility of a particular solute. Common ions from other solutes can reduce the solubility of a compound that shares those ions.
Depending on the amount of solute present in a solvent, solutions can be categorised into three types:
The concentration of a solution can be expressed in different ways, each providing insight into the relative amounts of solute and solvent.
These concentration percentages help describe how much solute is present in relation to the solution as a whole, whether by mass or by volume. They are commonly used in various fields, such as chemistry, pharmacy, and medicine, to accurately communicate the strength or composition of solutions.
The formulas for different concentration measurements are:
a) Mass by Mass Percentage (w/w%): This measures the mass of the solute in grams per 100 grams of the entire solution.
Formula:
b) Mass by Volume Percentage (w/v%): This measures the mass of the solute in grams per 100 millilitres of the solution.
Formula:
c) Volume by Volume Percentage (v/v%): This measures the volume of the solute in millilitres per 100 millilitres of the solution.
Formula:
The separation of mixtures is the process of isolating different substances or components from a mixture by using various methods based on their physical properties. Mixtures are combinations of two or more substances that are not chemically bonded together, and they can be composed of solids, liquids, or gases.
Different substances in a mixture can have distinct properties such as solubility, volatility, density, and boiling points. To extract specific components or substances from a mixture, various techniques are employed. Here are some common methods of separation:
1. Can an element exist in different forms but still be considered pure?
Yes, an element can exist in different forms known as allotropes but is still considered a pure substance. For example, carbon exists as graphite and diamond, which are different structural forms (allotropes) but are still made of pure carbon atoms.
2. Can a pure substance be separated by physical methods?
No, a pure substance cannot be separated into its components by physical methods (such as filtration or distillation) because its components are chemically bonded. It can only be separated by chemical reactions.
3. Is there a limit to how concentrated a solution can be?
Yes, the concentration of a solution has a limit, known as the saturation point. Once this point is reached, no more solute can dissolve in the solvent at a given temperature, and any additional solute will remain undissolved.
4. Does the type of solvent affect solubility?
Yes, the type of solvent significantly affects solubility. Polar solvents like water dissolve polar substances (like salt) well, while non-polar solvents like oil dissolve non-polar substances (like fat). "Like dissolves like" is a common rule of thumb in solubility.
5. Why is rusting considered a chemical change?
Rusting is considered a chemical change because iron reacts with oxygen in the presence of water to form iron oxide (rust), a new substance with different properties from iron.
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